A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester

Akshaya Kumar Samal; Haibo Zhu; Moussab Harb; Shiv Sangaru; Dalaver H. Anjum; Mohamed N. Hedhili; Youssef Saih; Jean-Marie Basset

doi:10.1039/c6cy02187e

A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester

Akshaya Kumar Samal, Haibo Zhu, Moussab Harb, Shiv Sangaru, Dalaver H. Anjum, Mohamed N. Hedhili, Youssef Saih, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C2H5)(3)H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

Original language	English (US)
Pages (from-to)	581-586
Number of pages	6
Journal	Catal. Sci. Technol.
Volume	7
Issue number	3
DOIs	https://doi.org/10.1039/c6cy02187e
State	Published - 2017

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title = "A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester",

abstract = "A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C2H5)(3)H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.",

author = "Samal, {Akshaya Kumar} and Haibo Zhu and Moussab Harb and Shiv Sangaru and Anjum, {Dalaver H.} and Hedhili, {Mohamed N.} and Youssef Saih and Jean-Marie Basset",

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T1 - A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester

AU - Samal, Akshaya Kumar

AU - Zhu, Haibo

AU - Harb, Moussab

AU - Sangaru, Shiv

AU - Anjum, Dalaver H.

AU - Hedhili, Mohamed N.

AU - Saih, Youssef

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2017

Y1 - 2017

N2 - A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C2H5)(3)H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

AB - A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C2H5)(3)H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

UR - http://hdl.handle.net/10754/623779

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2017/CY/C6CY02187E#!divAbstract

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DO - 10.1039/c6cy02187e

M3 - Article

SN - 2044-4753

VL - 7

SP - 581

EP - 586

JO - Catal. Sci. Technol.

JF - Catal. Sci. Technol.

IS - 3

ER -

A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester

Abstract

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