A “Branched‐Monomer Approach” for the Rapid Synthesis of Dendimers

Karen L. Wooley; Craig J. Hawker; Jean M.J. Fréchet

doi:10.1002/anie.199400821

A “Branched‐Monomer Approach” for the Rapid Synthesis of Dendimers

Karen L. Wooley, Craig J. Hawker, Jean M.J. Fréchet^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

115 Scopus citations

Abstract

An accelerated route to the synthesis of dendritic macromolecules through the use of fractal components larger than the repeating unit is described. The first‐generation bromide 1 and the second‐generation novel branched AB₄ monomer 2 can be used to prepare a highly regular fifth‐generation poly(ether ester) dendrimer (M_r = 9371) in only three synthetic steps. (Figure Presented.)

Original language	English (US)
Pages (from-to)	82-85
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	1
DOIs	https://doi.org/10.1002/anie.199400821
State	Published - Jan 17 1994
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199400821

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abstract = "An accelerated route to the synthesis of dendritic macromolecules through the use of fractal components larger than the repeating unit is described. The first‐generation bromide 1 and the second‐generation novel branched AB4 monomer 2 can be used to prepare a highly regular fifth‐generation poly(ether ester) dendrimer (Mr = 9371) in only three synthetic steps. (Figure Presented.)",

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AB - An accelerated route to the synthesis of dendritic macromolecules through the use of fractal components larger than the repeating unit is described. The first‐generation bromide 1 and the second‐generation novel branched AB4 monomer 2 can be used to prepare a highly regular fifth‐generation poly(ether ester) dendrimer (Mr = 9371) in only three synthetic steps. (Figure Presented.)

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A “Branched‐Monomer Approach” for the Rapid Synthesis of Dendimers

Abstract

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