4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes

Alexander Schoedel; Michael Jaquier; Wesley Boyette; Łukasz Wojtas; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1021/cg500205f

4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes

Alexander Schoedel, Michael Jaquier, Wesley Boyette, Łukasz Wojtas, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. © 2014 American Chemical Society.

Original language	English (US)
Pages (from-to)	2115-2117
Number of pages	3
Journal	Crystal Growth & Design
Volume	14
Issue number	5
DOIs	https://doi.org/10.1021/cg500205f
State	Published - Apr 14 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): FIC/2010/06
Acknowledgements: This work was partially supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST).

ASJC Scopus subject areas

General Materials Science
General Chemistry
Condensed Matter Physics

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10.1021/cg500205f

Cite this

@article{9d9b304033174560aa785e42a69d6311,

title = "4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes",

abstract = "A two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. {\textcopyright} 2014 American Chemical Society.",

author = "Alexander Schoedel and Michael Jaquier and Wesley Boyette and {\L}ukasz Wojtas and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This work was partially supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST).",

year = "2014",

month = apr,

day = "14",

doi = "10.1021/cg500205f",

language = "English (US)",

volume = "14",

pages = "2115--2117",

journal = "Crystal Growth & Design",

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T1 - 4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes

AU - Schoedel, Alexander

AU - Jaquier, Michael

AU - Boyette, Wesley

AU - Wojtas, Łukasz

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This work was partially supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST).

PY - 2014/4/14

Y1 - 2014/4/14

N2 - A two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. © 2014 American Chemical Society.

AB - A two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. © 2014 American Chemical Society.

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U2 - 10.1021/cg500205f

DO - 10.1021/cg500205f

M3 - Article

SN - 1528-7483

VL - 14

SP - 2115

EP - 2117

JO - Crystal Growth & Design

JF - Crystal Growth & Design

IS - 5

ER -

4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes

Abstract

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CCDC 1010339: Experimental Crystal Structure Determination : catena-[hexakis(mu-isonicotinato)-(mu-oxo)-tris(mu-thiophene-2,5-dicarboxylate)-hydroxo-diaqua-tri-chromium-tri-zinc unknown solvate]

CCDC 1010338: Experimental Crystal Structure Determination : catena-[hexakis(mu-isonicotinato)-(mu-oxo)-tris(mu-benzene-1,4-dicarboxylato)-hydroxo-diaqua-tri-chromium-tri-zinc unknown solvate]

Cite this

4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1010339: Experimental Crystal Structure Determination : catena-[hexakis(mu-isonicotinato)-(mu-oxo)-tris(mu-thiophene-2,5-dicarboxylate)-hydroxo-diaqua-tri-chromium-tri-zinc unknown solvate]

CCDC 1010338: Experimental Crystal Structure Determination : catena-[hexakis(mu-isonicotinato)-(mu-oxo)-tris(mu-benzene-1,4-dicarboxylato)-hydroxo-diaqua-tri-chromium-tri-zinc unknown solvate]

Cite this