2,7-Bis(diarylamino)-9,9-dimethylfluorenes as Hole-Transport Materials for Organic Light-Emitting Diodes

Richard D. Hreha*, Candace P. George, Andreas Haldi, Benoit Domercq, Massimo Malagoli, Stephen Barlow, Jean Luc Brédas, Bernard Kippelen, Seth R. Marder

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

86 Scopus citations


2,7-Bis(p-methoxyphenyl-m′-tolylamino)-9,9-dimethylfluorene (1′), 2,7-bis(phenyl-m′-tolylamino)-9,9-dimethylfluorene (2′) and 2,7-bis(p-fluorophenyl-m′-tolylamino)-9,9-dimethylfluorene (3′) have been synthesized using the palladium-catalyzed reaction of the appropriate diarylamines with 2,7-dibromo-9,9-dimethylfluorene. These molecules have glass-transition temperatures 15-20 °C higher than those for their biphenyl-bridged analogues, and are 0.11-0.14 V more readily oxidized. Fluorescence spectra and fluorescence quantum yields for dimethylfluorene-bridged and biphenyl-bridged species are similar, but the peaks of the absorption spectra of 1′-3′ are considerably red-shifted relative to those of their biphenyl-bridged analogues. Time-offlight hole mobilities of 1′-3′/polystyrene blends are in a similar range to those of the biphenyl-bridged analogues. Analysis according to the disorder formalism yields parameters rather similar to those for the biphenyl species, but with somewhat lower zero-field mobility values. Density functional theory (DFT) calculations suggest that the enforced planarization of the fluorene bridge leads to a slightly larger reorganization energy for the neutral/cation electron-exchange reaction than in the biphenylbridged system. Organic light-emitting diodes have been fabricated using 1′-3′/polystyrene blends as the hole-transport layer and tris(8-hydroxy quinoline)aluminium as the electron-transport layer and lumophore. Device performance shows a correlation with the ionization potential of the amine materials paralleling that seen in biphenyl-based systems, and fluorene species show similar performance to biphenyl species with comparable ionization potential.

Original languageEnglish (US)
Pages (from-to)967-973
Number of pages7
JournalAdvanced Functional Materials
Issue number12
StatePublished - Dec 2003
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • General Chemistry
  • Condensed Matter Physics
  • General Materials Science
  • Electrochemistry
  • Biomaterials


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