1-D polymer containing the [Ru–N–Ru] μ-nitrido moiety: crystal structure and magnetic properties of ([Cu(en)2]3[Ru2N(CN)10]·ClO4)n (en = 1,2-diaminoethane)

Xian Ru Sun, Jiang Lin Liang, Chi Ming Che*, Nianyong Zhu, X. X. Zhang, Song Gao

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

A novel (μ-nitrido–diruthenium)-bridged 1-D coordination polymer was formed from reaction of K5[Ru2N(CN)10] with [Cu(en)2](ClO4)2; a similar reaction with [Cu(pn)2][(ClO4)2] (pn = 1,3-diaminopropane) gave ([Cu(pn)2]5[Ru2N(CN)10]2) as a discrete molecular compound; variable temperature susceptibility measurements show that there is a weak ferromagnetic interaction between the Cu(II) ions in 1-D polymer.

Original languageEnglish (US)
Pages (from-to)2090-2091
Number of pages2
JournalCHEMICAL COMMUNICATIONS
Volume2
Issue number18
DOIs
StatePublished - 2002
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint

Dive into the research topics of '1-D polymer containing the [Ru–N–Ru] μ-nitrido moiety: crystal structure and magnetic properties of ([Cu(en)2]3[Ru2N(CN)10]·ClO4)n (en = 1,2-diaminoethane)'. Together they form a unique fingerprint.

Cite this